Meet Inspiring Speakers and Experts at our 3000+ Global Conference Series LLC LTD Events with over 1000+ Conferences, 1000+ Symposiums
and 1000+ Workshops on Medical, Pharma, Engineering, Science, Technology and Business.

Explore and learn more about Conference Series LLC LTD : World’s leading Event Organizer


5th International Conference on Organic and Inorganic Chemistry

Paris, France

Ali Ourari

Ali Ourari

Université Ferhat ABBAS Sétif

Title: A novel ferrocenic metal complexes Salen-like, derived from 5-chloromethyl-2-hydroxyacetophenone and N-ferrocenmethylaniline: Design, spectral approach and solvent effect with their electropolymerizable behavior for elaboration of modified electrodes


Biography: Ali Ourari


The research project of this work may be summarized in the synthesis, spectroscopic characterizations and electrochemical behavior of the tetradentate copper (II)-Schiff base complex[1] with its two wings as ferrocenylaniline moieties[2]. This new ferrocenic derivative with two ferrocenylaniline entities surrounding the copper (II)-Salen complex (5) was synthesized from N-ferrocenmethyl-N-phenyl-5-aminomethyl-2-hydroxyacetophenone (3) and one half equivalent of 1,2-diaminoethane in absolute ethanol. As for the intermediates involved in this synthetic sequence, the compound (3) was prepared in tetrahydrofuran (THF) by reacting N-ferrocenmethylaniline (2) with 5-chloromethyl-2-hydroxyacetophenone[3] (1) in presence of sodium hydrogenocarbonate (NaHCO3). The compound (3) condensed on the diamine yields the Schiff base ligand[4] (4)  which reacts with copper acetate monohydrate yielding the tetradentate Cu(II)-Schiff base complex (5). Their purities were estimated from elemental analysis while the molecular structures were elucidated with FT-IR, UV–Vis, 1H- and 13C- NMR. The electrochemical behaviors of the synthesized compounds were investigated using cyclic voltammetry in diverse solvents like dichloromethane (DC), acetonitrile (AN), dimethylformamide (DMF) and dimethylsulfoxide (DMSO). The anilinic entity grafted on these compounds may be modulated by using other electropolymerizable units as pyrrole,  thiophene and carbazole etc.