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Neliswa Mama

Neliswa Mama

Nelson Mandela University

Title: Synthesis and applications of fluorescent poly(coumarin-triazole) for metal ion sensing

Biography

Biography: Neliswa Mama

Abstract

Over the past few years, several analytical techniques for the determination of metal ions have been developed.  These include, spectrophotometry, inductively coupled plasma mass spectrometry (ICP-MS), inductively coupled plasma atomic emission spectrometry (ICP-AES), voltammetric, atomic fluorescence spectrometry (AFS), cold vapor atomic absorption spectroscopy (CV-AAS) and neutron activation analysis.  The disadvantages of these methods is that, they require expensive instruments, well-controlled experimental conditions, time consuming and complicated sample preparations.1   On the other hand, the use of chemosensors has attracted a great deal of attention due to their simplicity and selective for the detection of metal ions.  

The application of fluorescent conjugated polymers as chemosensors for metal ions has been a powerful tool in the recent years1. The use of these chemosensors have attracted considerable attention due to their ability to detect metal ions at very low concentrations2-3

In this study, fluorescent poly(coumarin-triazole) A and B were prepared in excellent yields by a well-established Cu(I)-catalysed click polymerization.  The application of these novel polymers as chemosensors was investigated using a range of metal ions.